Chapter Three should need no added support, so I have passed over to chapter four.
This chapter of the book is probably the most difficult for all of you, even if you do have some background in science. To be very honest there is no science required that is not covered in the Virginia SOL but I know most of you probably did this, or the equivalent, a long time ago. The aim of this chapter is to introduce you to the physical science behind volcanology, and although there really is nothing beyond you, I do not expect you to “get” it all. Just try. I will point out some of the things you should try to take with you to the rest of the course.
Magma
Magma is complex stuff. It is a chemical mix of different oxides of the metals Fe, Mg, Ca, Na, K, Al, Si with minor Ti, Cr, Ni, Zr and a host of other trace elements present in quantities measured only in parts per million. It is, however, not just a simple mixing bowl. These metal oxides are not distributed at all evenly throughout the melt. A better way to think of magma is of a matrix, or a mesh. Think of a bowl of spaghetti, (but even more “joined up) made from Oxygen (O) Silicon (Si) and Aluminum (Al) with the other oxides such as Iron, Magnesium, Calcium, Sodium and Potassium occupying the holes. The more joined up the spaghetti (the greater the degree of polymerization) the more viscous (harder to stir) it becomes. In this bowl of magma, water acts like a pair of scissors, cutting up the matrix into smaller pieces that flow past each other more easily, and thus the magma becomes less viscous (easier to stir). An important by product of this is that that the other metal oxides are then able to diffuse (move) through the melt more easily. This allows crystals to grow faster and bubbles to form larger -and faster too.
Magma chambers are not usually simple caverns in the ground. In most cases they are very complex (well they just had to be, right?) and take many forms. There are cases, especially in high level magma chambers (i.e. not too deep in the crust), where such “caverns” of magma may form, even within the the actual physical edifice of a volcano, but more often chambers are much more complex; more like a sponge, where the surrounding rock (country rock) is the sponge, with magma as water in the sponge. In this case the magma often partially melts some of the country rock that then mixes with the magma as it cools and crystallizes. Even as this happy hadean fusion is consummated, more fresh magma will well up from below to replenish and reheat the magma that was emplaced earlier. This is a dynamic and interactive process that has the potential to produce a broad range of magma compositions and many different forms of volcanic eruption.
Bubbles
Until you have stared thoughtfully at the bubbles in as many pints of Guinness as I have, you could not have the slightest clue just how complex bubbles can be. This section tells a simple tale for you to remember. Bubbles grow in magma in the same way as they do in any fizzy drink. Gas is dissolved in the magma until the pressure drops enough for it to be released (open the can!). As magma rises to the surface, and the pressure drops, bubbles start to form. In low viscosity magma, such as basalt, the bubbles can form easily, grow large, and can escape from the magma relatively easily. In MORE viscous magma (complex spaghetti) like rhyolite, the bubbles find it hard to form, and are not able to grow so large. As a consequence pressure inside the bubbles builds up. Think of blowing some air into a large balloon, and then the same amount of air into a small balloon. The small balloon builds up pressure until the surrounding rubber breaks and the balloon bursts. Well, this also happens with bubbles in viscous magma. The pressure builds up to the point where the surrounding magma, stretched to breaking point in an incandescent froth, fractures under the pressure of all these bubbles to produce an almighty explosion, and a subsequent violent eruption, not of magma, but of a fragmented foam of magma and gas. This is a classic pyroclastic eruption.