{"id":1046,"date":"2021-05-28T11:38:46","date_gmt":"2021-05-28T15:38:46","guid":{"rendered":"https:\/\/blog.richmond.edu\/chemistryofcooking\/?page_id=1046"},"modified":"2021-05-28T11:38:46","modified_gmt":"2021-05-28T15:38:46","slug":"water-activity-and-cookie-softness","status":"publish","type":"page","link":"https:\/\/blog.richmond.edu\/chemistryofcooking\/water-activity-and-cookie-softness\/","title":{"rendered":"Water Activity and Cookie Softness"},"content":{"rendered":"<p><strong>Water activity<\/strong>\u00a0affects the physical properties of foods. Foods with a\u00a0<em><strong>high water activity<\/strong><\/em>\u00a0have a texture that is moist, juicy, tender, and chewy. When the water activity of these products is lowered, you get hardness, dryness, staleness, and toughness.\u00a0<strong><em>Low water activity<\/em><\/strong>\u00a0products have texture attributes described as crisp and crunchy, while these products at higher water activity\u00a0levels change to a soggy texture.<sup>1<\/sup><\/p>\n<p>When water interacts with ionic and polar molecules, the closest water molecules are held or \u201ctied up\u201d making them unavailable\u00a0 for other uses. The remaining water is \u201cfree\u201d or \u201cbulk\u201d water. Sugar molecules are\u00a0<em>excellent<\/em>\u00a0at tying up the water and holding onto it because of a sugar&#8217;s capacity to form many\u00a0<em>hydrogen bonds<\/em>\u00a0with water.<\/p>\n<p><img loading=\"lazy\" decoding=\"async\" src=\"https:\/\/muhlenbergcollege.instructure.com\/courses\/6764\/files\/333153\/download?verifier=rCWtYHdlYGTiSYQsXbJleXYZvnTR9458v3wDM96w&amp;wrap=1\" alt=\"Glucose and water hydrogen bonding\" width=\"616\" height=\"489\" data-api-endpoint=\"https:\/\/muhlenbergcollege.instructure.com\/api\/v1\/courses\/6764\/files\/333153\" data-api-returntype=\"File\" \/><\/p>\n<p>~An image of glucose\u00a0<em>hydrogen bonding<\/em>\u00a0with water from Lesson 3.<\/p>\n<p>&nbsp;<\/p>\n<h2>Water activity: it\u2019s all about energy<sup>2<\/sup><\/h2>\n<p>Take a glass of water and a dry sponge. Dip the corner of the sponge into the glass of water. The water will move from the glass into the sponge.<\/p>\n<p>Water activity is the force that causes the water to move into the sponge. To understand it better, think about how the water in the sponge is different from the water in the glass.<\/p>\n<p>The water in the glass is free, but the water in the sponge is anything but free. It\u2019s bound by hydrogen bonds. These are called matrix effects. The water in the sponge has a lower energy state than the water in the glass. Water will flow into the sponge, but to get it back out, we must do work by squeezing the sponge.<\/p>\n<p>In your cookie,\u00a0<em>sugar<\/em>\u00a0is the &#8220;sponge&#8221; that is holding onto the water.<\/p>\n<p>&nbsp;<\/p>\n<h2>How does this impact my cookies?<\/h2>\n<p>In your lab, you examined the effect of fat on the cookie &#8211; butter vs. olive oil, or shortening.<\/p>\n<p><img decoding=\"async\" src=\"https:\/\/muhlenbergcollege.instructure.com\/courses\/6764\/files\/333161\/download?verifier=KXxZ6Uv4RkH8yaQLYjk5cjDVs4s4fInIUL3fOAG9&amp;wrap=1\" alt=\"Butter fat and moisture content\" data-api-endpoint=\"https:\/\/muhlenbergcollege.instructure.com\/api\/v1\/courses\/6764\/files\/333161\" data-api-returntype=\"File\" \/><\/p>\n<p>Butter has ~15% water in it, ~80% fat and ~5% milk protein and sugars.<sup>3<\/sup>\u00a0This is because butter comes\u00a0from milk, a watery liquid; it&#8217;s a normal part of the butter making process. Oils and Shortening however are 100% fat. What would you expect from two sugary baked goods that are identical,\u00a0<em>except<\/em>\u00a0one is made with a fat source that contains ~15% water, and the other uses a fat source that is 100% fat?<\/p>\n<p>Borrowed from: <a href=\"https:\/\/muhlenbergcollege.instructure.com\/courses\/6764\/pages\/water-activity-and-cookie-softness\" target=\"_blank\" rel=\"noopener\">Muhlenberg College<\/a><\/p>\n<h5>References:<\/h5>\n<p>(1)\u00a0<a class=\"external\" href=\"https:\/\/www.metergroup.com\/food\/articles\/use-water-activity-to-get-and-maintain-the-right-texture-meter\/\" target=\"_blank\" rel=\"noreferrer noopener\">https:\/\/www.metergroup.com\/food\/articles\/use-water-activity-to-get-and-maintain-the-right-texture-meter\/<span class=\"screenreader-only\">\u00a0(Links to an external site.)<\/span><\/a><\/p>\n<p>(2)\u00a0<a class=\"external\" href=\"https:\/\/www.metergroup.com\/food\/articles\/introduction-to-water-activity\/\" target=\"_blank\" rel=\"noreferrer noopener\">https:\/\/www.metergroup.com\/food\/articles\/introduction-to-water-activity\/<span class=\"screenreader-only\">\u00a0(Links to an external site.)<\/span><\/a><\/p>\n<p>(3)\u00a0<a class=\"external\" href=\"https:\/\/www.sfgate.com\/recipes\/article\/When-Put-to-the-Test-Here-s-How-Butter-Brands-3236719.php#photo-2380112\" target=\"_blank\" rel=\"noreferrer noopener\">https:\/\/www.sfgate.com\/recipes\/article\/When-Put-to-the-Test-Here-s-How-Butter-Brands-3236719.php#photo-2380112<span class=\"screenreader-only\">\u00a0(Links to an external site.)<\/span><\/a><\/p>\n","protected":false},"excerpt":{"rendered":"<p>Water activity\u00a0affects the physical properties of foods. Foods with a\u00a0high water activity\u00a0have a texture that is moist, juicy, tender, and chewy. When the water activity of these products is lowered, you get hardness, dryness, staleness, and toughness.\u00a0Low water activity\u00a0products have &hellip; <a href=\"https:\/\/blog.richmond.edu\/chemistryofcooking\/water-activity-and-cookie-softness\/\">Continue reading <span class=\"meta-nav\">&rarr;<\/span><\/a><\/p>\n","protected":false},"author":1230,"featured_media":0,"parent":0,"menu_order":0,"comment_status":"closed","ping_status":"closed","template":"","meta":{"footnotes":""},"coauthors":[142150],"class_list":["post-1046","page","type-page","status-publish","hentry"],"_links":{"self":[{"href":"https:\/\/blog.richmond.edu\/chemistryofcooking\/wp-json\/wp\/v2\/pages\/1046","targetHints":{"allow":["GET"]}}],"collection":[{"href":"https:\/\/blog.richmond.edu\/chemistryofcooking\/wp-json\/wp\/v2\/pages"}],"about":[{"href":"https:\/\/blog.richmond.edu\/chemistryofcooking\/wp-json\/wp\/v2\/types\/page"}],"author":[{"embeddable":true,"href":"https:\/\/blog.richmond.edu\/chemistryofcooking\/wp-json\/wp\/v2\/users\/1230"}],"replies":[{"embeddable":true,"href":"https:\/\/blog.richmond.edu\/chemistryofcooking\/wp-json\/wp\/v2\/comments?post=1046"}],"version-history":[{"count":2,"href":"https:\/\/blog.richmond.edu\/chemistryofcooking\/wp-json\/wp\/v2\/pages\/1046\/revisions"}],"predecessor-version":[{"id":1049,"href":"https:\/\/blog.richmond.edu\/chemistryofcooking\/wp-json\/wp\/v2\/pages\/1046\/revisions\/1049"}],"wp:attachment":[{"href":"https:\/\/blog.richmond.edu\/chemistryofcooking\/wp-json\/wp\/v2\/media?parent=1046"}],"wp:term":[{"taxonomy":"author","embeddable":true,"href":"https:\/\/blog.richmond.edu\/chemistryofcooking\/wp-json\/wp\/v2\/coauthors?post=1046"}],"curies":[{"name":"wp","href":"https:\/\/api.w.org\/{rel}","templated":true}]}}